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High-valent iron alkyl complexes are rare, as they are prone to Fe–C bond homolysis. Here, we describe an unusual way to access formally iron(iv) alkyl ...
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Scientific publisher of biology, biophysics, chemical science, materials, medicinal drug discovery and physics high-impact journals and books.
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https://doi.org/10.1039/D4SC90040E. Article type: Front/Back Matter. First published: 22 Feb 2024. This article is Open Access All publication charges for this article have been paid for by the Royal Society of Chemistry: Creative Commons BY license ...
Mild and catalytic electrocyclizations of heptatrienyl anions
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We report the synthesis of functionalized cycloheptanes by thermal electrocyclization of heptatrienyl anions under mild conditions. In addition, we disclose ...
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This 2-stannapropadiene features a 119Sn NMR signal at 507 ppm for the central tin atom, indicative of an unsaturated Sn4+ oxidation state. Due to the inert- ...
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We report the investigation of the black film formed on the surface of the anodes in aHF by an in situ Ni K-edge X-ray absorption near edge structure (XANES) ...
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Herein, a metal- and photosensitizer-free protocol has been developed for decarboxylative C–H (amino)alkylation of heteroarenes using carboxylic acids as ...
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